Chemistry

Distinguish between the following as directed:

(a) Sodium Sulphite and Sodium Sulphate by using dilute HCl.

(b) Ammonium chloride and Sodium chloride by using Calcium hydroxide.

(c) Lead nitrate and silver nitrate by using HCl.

Practical Chemistry

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Answer

(a) When Sodium sulphite reacts with HCl, effervescence occurs and a pungent gas (SO2) is evolved that turns acidified potassium dichromate paper from orange to green.

Na2SO3 + 2HCl ⟶ 2NaCl + H2O + SO2

Whereas, Sodium sulphate (Na2SO4) gives no visible reaction with HCl and no gas is evolved.

(b) Ammonium Chloride (NH4Cl) reacts with Ca(OH)2 to release ammonia gas (NH3) which has pungent smell, turns red litmus blue.

2NH4Cl + Ca(OH)2 ⟶ CaCl2 + 2H2O + 2NH3

Whereas, sodium chloride shows no reaction with Calcium hydroxide.

(c) Lead Nitrate (Pb(NO3)2) reacts with HCl, forms a white precipitate of lead chloride (PbCl2) which is soluble in hot water.

Pb(NO3)2 + 2HCl ⟶ PbCl2 ↓ + 2HNO3

However, when Silver nitrate reacts with HCl, it forms a white precipitate of silver chloride (AgCl) which is insoluble in hot water

AgNO3 + HCl ⟶ AgCl ↓ + HNO3

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