Chemistry

Which of the following arrangements is INCORRECT as per the property stated against it?

  1. Li > Be > N > O (Metallic character)
  2. CI > F > Br > I (Electron gain enthalpy)
  3. O2- > F - > Mg2+ > Na+(Ionic radii)
  4. I > Br > CI > F (Number of shells)

Periodic Table

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Answer

O2- > F - > Mg2+ > Na+(Ionic radii)

Reason

Periodic propertyArrangementExplanation
Metallic characterLi > Be > N > OMetallic character decreases across a period from left to right
Electron gain enthalpyCI > F > Br > IElectron gain enthalpy generally becomes less negative down a group
Ionic radiiO2- > F - > Mg2+ > Na+Ionic radius of isoelectronic species (same number of electrons), decreases with increasing nuclear charge
Number of shellsI > Br > CI > FNumber of shells increases down the group. I has the most shells

In case of ionic radius, O2- > F - > Mg2+ > Na+ has 10 electrons each, Atomic numbers(Z) of O = 8, F = 9, Na = 11, Mg = 12, Higher the Z, greater is the attraction and smaller is the radius.

The correct order would be, O2- > F - > Na+ > Mg2+.

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