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Chemistry

A sample of ammonium nitrate when heated yields 8.96 litres of steam (measured at STP)

NH4NO3 ⟶ N2O + 2H2O

(i) What volume of di nitrogen oxide is produced at the same time as 8.96 litres of steam ?

(ii) What mass of ammonium nitrate should be heated to produce 8.96 litres of steam ? [Relative molecular mass of ammonium nitrate, NH4NO3 is 80]

(iii) Determine the percentage of oxygen in ammonium nitrate [O = 16]

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Answer

NH4NO3ΔN2O+2H2O1 vol.=80g1 vol.2 vol.\begin{matrix} \text{NH}4\text{NO}3 &\xrightarrow{\Delta} & \text{N}2\text{O} & + & 2\text{H}2\text{O} \ 1\text{ vol.} = 80 \text{g} & & 1 \text{ vol.} & & 2\text{ vol.} \ \end{matrix}

(i) Given,

1 vol. of di nitrogen produced at the same time as 8.96 litres of steam (2 vol)

Hence, Vol of di nitrogen = 8.962\dfrac{8.96}{2} = 4.48 lit.

Hence, volume of di nitrogen oxide produced = 4.48 lit.

(ii) 2 vol = (2 x 22.4) lit steam is produced from 80 g NH4NO3

∴ 8.96 lit of steam will be produced by 802×22.4\dfrac{80}{2 \times 22.4} x 8.96 = 16 g

Hence, 16 g of ammonium nitrate is required to be heated.

(iii) % of oxygen in ammonium nitrate = 3×1680\dfrac{3 \times 16}{80} x 100 = 60 %

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