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Chemistry

(a) State the condition required for the following reactions.

(1) Conversion of methyl chloride to dichloromethane.

(2) Conversion of ethanol to ethene.

(b) Give the reaction involved in the formation of methyl acetate (ester).

Organic Chemistry

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Answer

(a) (1) methyl chloride converts to dichloromethane under diffused sunlight, ultraviolet light or high temperature [400°C]

CH3Clmethylchloride+Cl2[excess]CH2Cl2dichloromethane+HCl\underset{\text{methylchloride} }{\text{CH}3\text{Cl}} + \underset{\text{[excess]}}{\text{Cl}2} \longrightarrow \underset{\text{dichloromethane}}{\text{C}\text{H}2\text{Cl}2}+ \text{HCl}

(2) By heating ethyl alcohol with concentrated H2SO4 at 170°C.

C2H5OH ethyl alcohol170°CConc. H2SO4[excess]C2H4ethene+H2O\underset{\text{ ethyl alcohol}}{\text{C}2\text{H}5\text{OH}} \xrightarrow[170\degree\text{C}]{\text{Conc. H}2\text{SO}4\text{[excess]}} \underset{ \text{ethene}}{\text{C}2\text{H}4} + \text{H}_2\text{O}\

(b)

CH3OHmethyl alcohol+CH3COOHacetic acidConc. H2SO4CH3COOCH3methyl acetate+H2O\underset{\text{methyl alcohol}}{\text{CH}3\text{OH}} + \underset{\text{acetic acid}}{\text{CH}3\text{COOH}} \xrightarrow{\text{Conc. H}2\text{SO}4} \underset{\text{methyl acetate}}{\text{CH}3-\text{COO}-\text{CH}3} + \text{H}_2\text{O}

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