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Chemistry

(a) Write the cell reaction for the electrolysis of dil. AgNO3 solution using Ag anode and Cu cathode.

(b) Name a compound of ammonia which sublimes on heating?

(c) Name the gas evolved on reaction of aluminium with boiling concentrated caustic alkali solution, write the equation.

Electrolysis

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Answer

(a) AgNO3 ⇌ Ag+ + NO3-

H2O ⇌ H+ + OH-

Reaction at anode :
4OH- - 4e- ⟶ 4OH
4OH ⟶ 2H2O + O2

Reaction at cathode :
H+ + 1e- ⟶ H
H + H ⟶ H2

(b) Ammonium chloride

(c) Hydrogen gas is evolved

2Al + 2NaOH + 2H2O ⟶ 2NaAlO2 + 3H2

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