Chemistry

Assertion (A): On adding ammoniacal silver nitrate to ethyne, it gives a white precipitate.

Reason (R): The above reaction forms silver acetylide.

  1. Both A and R are true and R is the correct explanation of A.
  2. Both A and R are true but R is not the correct explanation of A.
  3. A is true but R is false.
  4. A is false but R is true.

Organic Chemistry

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Answer

Both A and R are true and R is the correct explanation of A.

Explanation— Ethyne (HC≡CH) reacts with ammoniacal silver nitrate to give a white precipitate of silver acetylide (AgC≡CAg). Thus Assertion (A) is correct. The precipitate’s identity—silver acetylide—explains why the white solid appears, so Reason (R) is also true and provides the correct explanation for the assertion.

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