Chemistry

Assertion (A): Alkynes show addition reactions.

Reason (R): Alkanes show substitution reactions.

  1. Both A and R are true and R is the correct explanation of A.
  2. Both A and R are true but R is not the correct explanation of A.
  3. A is true but R is false.
  4. A is false but R is true.

Organic Chemistry

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Answer

Both A and R are true but R is not the correct explanation of A.

Explanation— Alkynes contain a carbon–carbon triple bond, making them highly unsaturated; therefore they readily take part in addition reactions with hydrogen, halogens, etc. Hence, the assertion (A) is true.
Alkanes, being saturated hydrocarbons, usually react by substitution, for example, the replacement of a hydrogen atom by chlorine in the presence of ultraviolet light. Hence, the reason (R) is true.
While both statements are correct, the fact that alkanes undergo substitution does not explain why alkynes undergo addition, hence, reason (R) is not the correct explanation of assertion (A).

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