Science
(a) ‘A’ & ‘B’ are sodium salts of long-chain carboxylic acid and long chain Sulphonic acid respectively. Which one of A or B will you prefer as a cleansing agent while using underground water (hand pump water)? Give the reason for your answer.
(b) Elaborate on the process of cleansing action. Illustrate micelle with the help of labelled diagram.
(c) Write the chemical equation of the preparation of soap from an ester CH3COOCH3. What is the name of this process?
Organic Chemistry
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Answer
(a) ‘A’ is the sodium salt of a long-chain carboxylic acid, which means it is a soap, while ‘B’ is the sodium salt of a long-chain sulphonic acid, which is a synthetic detergent.
When underground water (hard water) is used, it contains calcium and magnesium ions and these ions react with soaps to form insoluble scum, which reduces the cleansing efficiency of soap.
However, detergents do not form scum with the ions present in hard water because the sulphonate group of the detergent does not react with calcium or magnesium ions.
Hence, ‘B’ (detergent) is preferred as a cleansing agent in underground (hard) water because it remains effective and forms more lather even in hard water.
(b) Cleansing action of soap :
- Soaps are molecules in which the two ends have differing properties, one is hydrophilic, that is, it dissolves in water, while the other end is hydrophobic, that is, it dissolves in hydrocarbons.
- The molecules of soap are sodium or potassium salts of long-chain carboxylic acids. The ionic end of soap dissolves in water while the carbon chain dissolves in oil. The soap molecules, thus form structures called micelles where one end of the molecules is towards the oil droplet while the ionic end faces outside. This forms an emulsion in water. The soap micelle thus helps in dissolving the dirt in water and we can wash our clothes clean.

(c) When an ester reacts with a strong base (NaOH), it forms a salt of carboxylic acid (soap) and an alcohol.
Chemical equation :
CH3COOCH3 + NaOH → CH3COONa + CH3OH
This process is called saponification.
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