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Chemistry

It is found, on heating a gas, its volume increases by 50% and pressure increased by 60% of its original value. If the original temperature was -15°C, find the temperature to which it was heated?

Gas Laws

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Answer

Initial conditions [S.T.P.] :

P1 = Initial pressure of the gas = P
V1 = Initial volume of the gas = V
T1 = Initial temperature of the gas = -15°C = -15 + 273 = 258 K

Final conditions :

P2 (Final pressure) = pressure increases by 60% of its original value

= 1 + 60100\dfrac{60}{100} of P

= 100+60100\dfrac{100 + 60}{100} of P

= 160100\dfrac{160}{100} of P

= 85\dfrac{8}{5}P

V2 (Final volume) = volume increases by 50% of its original value

= 1 + 50100\dfrac{50}{100} of V

= 100+50100\dfrac{100 + 50}{100} of V

= 150100\dfrac{150}{100} of V

= 32\dfrac{3}{2}V

T2 (Final temperature) = ?

By Gas Law:

P1×V1T1=P2×V2T2\dfrac{\text{P}1\times\text{V}1}{\text{T}1} = \dfrac{\text{P}2\times\text{V}2}{\text{T}2}

Substituting the values :

PV 258=85P×32VT2T2=8×3×2585×2=619210T2=619.2K\dfrac{\text{PV }}{258} = \dfrac{\dfrac{8}{5} \text{P}\times\dfrac{3}{2}\text{V}}{\text{T}2} \\[1em] \text{T}2 = \dfrac{8\times 3\times 258}{5 \times 2} = \dfrac{6192}{10} \\[1em] \text{T}_2 = 619.2 \text{K} \\[1em]

∴ Final temperature of the gas = 619.2 - 273 = 346.2°C

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