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Four statements about the reactions of oxides with dilute hydrochloric acid and aqueous sodium hydroxide are listed.

I. Aluminium oxide reacts with both dilute hydrochloric acid and aqueous sodium hydroxide.

II. Calcium oxide reacts with dilute hydrochloric acid and aqueous sodium hydroxide.

III. Zinc oxide reacts with both dilute hydrochloric acid and aqueous sodium hydroxide.

IV. Sulphur dioxide does not react with either dilute hydrochloric acid or aqueous sodium hydroxide.

Which statements are correct?

options

  1. I and II
  2. I and III
  3. II and IV
  4. III and IV

Acids Bases Salts

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Answer

I and III

Reason

  • Aluminium oxide (Al2O3) and zinc oxide (ZnO) are amphoteric in nature so they react with dilute HCl (acid) to form chlorides and with aqueous NaOH (base) to form soluble aluminates/zincates → I and III true.

  • Calcium oxide (CaO) is basic so it reacts only with dilute HCl but not with NaOH → II false.

  • Sulphur dioxide (SO2) is an acidic oxide so it does react only with NaOH (forming sulphite/bisulphite) though not with HCl → IV false.

Hence, statements I and III are correct.

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