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Chemistry

Give one significant observation when:

(a) a solution of barium chloride is added to zinc sulphate solution.

(b) lead nitrate is heated in a test tube.

(c) chlorine gas is passed over moist starch iodide paper.

Analytical Chemistry

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Answer

(a) When barium chloride solution is added to a solution of Zinc sulphate, white ppt. of barium sulphate is obtained which is insoluble in dil. HCl or nitric acid.

ZnSO4 + BaCl2 ⟶ BaSO4 ↓ [white ppt.] + ZnCl2

(b) When lead nitrate is heated in a test tube, brown fumes of nitrogen dioxide (NO2) are evolved and a yellow residue of lead(II) oxide remains.

2Pb(NO3)2 Δ\xrightarrow{\Delta} 2PbO + 4NO2 + O2

(c) The moist starch-iodide paper turns blue-black because chlorine liberates iodine from iodide.

Cl2 + 2KI ⟶ 2KCl + I2

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