Chemistry
Give reasons for the following:
In the laboratory preparation of nitric acid, the mixture of concentrated sulphuric acid and sodium nitrate should not be heated very strongly above 200°C.
Nitric Acid
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Answer
The temperature of the reaction should not increase above 200°C, because sodium sulphate formed at higher temperature, forms a hard crust which sticks to the walls of the retort and is difficult to remove, although the yield of nitric acid is higher.
2NaNO3 + H2SO4 Na2SO4 + 2HNO3
The higher temperature
- may damage the glass apparatus.
- decomposition of nitric acid can also occur.
- wastage of fuel.
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In the preparation of nitric acid from KNO3, Concentrated hydrochloric acid is not used in place of concentrated sulphuric acid. Explain why.
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(a) Nitric acid cannot be concentrated beyond 68% by the distillation of a dilute solution of HNO3. State the reason.
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