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Chemistry

How did Charles' law lead to the concept of an absolute scale of temperature?

Gas Laws

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Answer

According to Charles' law, when pressure (P) is constant,

V=V0+V0273tV=V0(273+t273)\text{V} = \text{V}0 + \dfrac{\text{V}0}{273}\text{t} \\[1em] \Rightarrow \text{V} = \text{V}_0\Big(\dfrac{273 + \text{t}}{273}\Big)

∴ Volume at -273°C = V0(273273273)\text{V}_0\Big(\dfrac{273 - 273}{273}\Big) = 0

Hence, the volume of a gas would be reduced to zero at -273°C. This temperature is called absolute zero.

This allowed the scientists to establish an absolute temperature scale (known as Kelvin scale) by defining absolute zero as the point where volume of a gas would theoretically be zero.

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