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The metals obtained from their molten chlorides by the process of electrolytic reduction are :

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  1. Gold and silver
  2. Calcium and magnesium
  3. Aluminium and silver
  4. Sodium and iron

Metallurgy

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Answer

Calcium and magnesium

Reason — Metals like calcium and magnesium are highly reactive and are obtained by the electrolytic reduction of their molten chlorides (CaCl2 and MgCl2).

During electrolysis, the metal ions are reduced at the cathode to form the pure metal and less reactive metals like gold, silver or iron are extracted by other methods and not by electrolysis of molten salts.

Hence, the metals obtained from their molten chlorides by the process of electrolytic reduction are calcium and magnesium.

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