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Chemistry

Prove that the volume of a gas at 273°C is twice its volume at 273 K, at constant pressure.

Gas Laws

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Answer

V1 = Initial volume of the gas = V

T1 = Initial temperature of the gas = 273 K

T2 = Final temperature of the gas = 273°C = 273 + 273 = 546 K

V2 = Final volume of the gas = ?

By Charles' Law:

V1T1=V2T2\dfrac{\text{V}1}{\text{T}1} = \dfrac{\text{V}2}{\text{T}2}

Substituting the values :

V273=V2546V2=V×546273V2=2V\dfrac{\text{V}}{273} = \dfrac{\text{V}2}{546} \\[1em] \text{V}2 = \dfrac{\text{V}\times 546}{273} \\[1em] \text{V}_2 = 2\text{V} \\[1em]

∴ Volume of a gas at 273°C is twice its volume at 273 K

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