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Chemistry

You are provided with some compounds in the box.

PbO CH4 PbO2 CO2
 HCl NCl3 SO2 

Choose the most appropriate compound which fits the descriptions (a) to (c) given below:

(a) A colourless gas which turns acidified K2Cr2O7 from orange to green.

(b) A yellow explosive oily liquid formed when excess chlorine gas reacts with ammonia gas.

(c) A yellow metallic oxide formed on thermal decomposition of PbCO3.

Practical Chemistry

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Answer

(a) SO2

Reason — Sulphur dioxide is a colourless gas. It is a reducing agent and turns acidified potassium dichromate solution from orange to green.

(b) NCl3

Reason — Nitrogen trichloride is a yellow explosive oily liquid formed when excess chlorine reacts with ammonia.

NH3 + 3Cl2 ​⟶ NCl3 + 3HCl

(c) PbO

Reason — Lead(II) oxide is yellow and is produced when lead carbonate (PbCO3) undergoes thermal decomposition.

PbCO3 ⟶ PbO + CO2

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