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Chemistry

(a) Write an equation for the laboratory preparation of

(i) An unsaturated hydrocarbon from calcium carbide.

(ii) An alcohol from ethyl bromide.

(b) What would you see, when ethyne is bubbled through a solution of bromine in carbon tetrachloride?

(c) Name the addition product formed between ethene and water.

Organic Chemistry

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Answer

(a) (i) Ethyne [C2H2] from Calcium Carbide :

CaC2calcium carbide+2H2OwaterC2H2ethyne+Ca(OH)2calcium hydroxide\underset{\text{calcium carbide}}{\text{CaC}2} + \underset{\text{water}}{2\text{H}2\text{O}} \longrightarrow \underset{\text{ethyne}}{\text{C}2\text{H}2} ↑ + \underset{\text{calcium hydroxide}}{\text{Ca(OH)}_2}

(ii) An alcohol from ethyl bromide.

C2H5-Br Bromoethane [ethyl bromide]+KOH [aq.]boilC2H5OH ethyl alcohol+KBr\underset{\text{ Bromoethane [ethyl bromide]}}{\text{C}2\text{H}5\text{-Br}} + \text{KOH [aq.]} \xrightarrow{\text{boil}} \underset{ \text{ ethyl alcohol}} {\text{C}2\text{H}5\text{OH}} + \text{KBr}

(b) Brown colour of bromine disappears when ethyne is bubbled through a solution of bromine in carbon tetrachloride.

C2H2 + Br2 ⟶ C2H2Br2 + Br2 ⟶ C2H2Br4

(c) Ethanol (C2H5OH)

C2H4 + H2O ⟶ C2H5OH

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