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Chemistry

Name the products formed and write an equation when ethyne is added to the following in an inert solvent:

(a) chlorine

(b) bromine

(c) iodine

(d) hydrogen

(e) excess of hydrochloric acid.

Organic Chemistry

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Answer

1,2-dichloro ethene and 1,1,2,2 -tetrachloro ethane will be formed.

C2H2 + Cl2 ⟶ C2H2Cl2 + Cl2 ⟶ C2H2Cl4

(b) Bromine

1,2-dibromo ethene and 1,1,2,2 -tetrabromo ethane will be formed.

C2H2 + Br2 ⟶ C2H2Br2 + Br2 ⟶ C2H2Br4

(c) Iodine

1,2-di-iodoethene will be formed.

C2H2 + I2 ⟶ ICH=CHI

(d) Hydrogen

Ethene and then ethane will be formed.

C2H2 Ethyne+H2NickleC2H4ethene+H2NickleC2H6ethane\underset{\text{ Ethyne}}{\text{C}2\text{H}2} + \text{H}2 \xrightarrow{\text{Nickle}} \underset{\text{ethene}}{\text{C}2\text{H}4} + \text{H}2 \xrightarrow{\text{Nickle}} \underset{\text{ethane}}{\text{C}2\text{H}6}

(e) Excess of hydrochloric acid.

Chloro ethene and then 1,1-dichloro ethane will be formed.

C2H2 Ethyne+ HClC2H3Clchloro ethene+ HClC2H4Cl21,1-dichloro ethane\underset{\text{ Ethyne}}{\text{C}2\text{H}2} \xrightarrow{\text{+ HCl}} \underset{\text{chloro ethene}}{\text{C}2\text{H}3\text{Cl}} \xrightarrow{\text{+ HCl}} \underset{\text{1,1-dichloro ethane}}{\text{C}2\text{H}4\text{Cl}_2}

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