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Chemistry

Calculate the volume (in cm3) of air expelled from a vessel containing 0.4 litres of it at 250 K, when it is heated to 27°C at the same pressure.

Gas Laws

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Answer

1 lit = 1000 cm3
∴ 0.4 lit = 400 cm3

V1 = Initial volume of the gas = 400 cm3
T1 = Initial temperature of the gas = 250 K
T2 = Final temperature of the gas = 27°C = 27 + 273 = 300 K
V2 = Final volume of the gas = ?

By Charles' Law:

V1T1=V2T2\dfrac{\text{V}1}{\text{T}1} = \dfrac{\text{V}2}{\text{T}2}

Substituting the values :

400250=V2300V2=400×300250V2=480 cm3\dfrac{400}{250} = \dfrac{\text{V}2}{300} \\[1em] \text{V}2 = \dfrac{400 \times 300}{250} \\[1em] \text{V}_2 = 480 \text{ cm}^3

Volume of air expelled = 480 - 400 = 80 cm3

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