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Chemistry

(i) Which concentrated acid will oxidize sulphur directly to sulphuric acid ? Write the equation for the same.

(ii) Complete the following : concentrated sulphuric acid is used in the laboratory preparation of nitric acid and hydrochloric acid because it is — (less volatile/stronger) in comparison to these two acids.

(iii) Write the observation and the balanced equation, when a paper dipped in acidified potassium dichromate solution is put on the mouth of a test tube containing sulphur dioxide gas.

Sulphuric Acid

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Answer

(i) Hot and conc. nitric acid.

S + 6HNO3 ⟶ H2SO4 + 2H2O + 6NO2

(ii) Concentrated sulphuric acid is used in the laboratory preparation of nitric acid and hydrochloric acid because it is less volatile in comparison to these two acids.

(iii) Acidified potassium dichromate solution changes to green colour from orange colour.

K2Cr2O7 + H2SO4 + 3SO2 ⟶ K2SO4 + Cr2(SO4)3 + H2O

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