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Chemistry

Why do 1735Cl^{35}{17}\text{Cl} and 1737Cl^{37}{17}\text{Cl} show a similar behaviour ? Atomic mass chlorine is 35.5. What is the ratio of 37Cl and 35Cl in chlorine?

Atomic Structure

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Answer

1735Cl^{35}{17}\text{Cl} and 1737Cl^{37}{17}\text{Cl} show a similar behaviour because they are isotopes of chlorine. They have the same atomic number (17) and same number of protons. They also have the same number of electrons in a neutral atom and same electronic configuration. Since, chemical properties depend mainly on electronic configuration, so both isotopes show similar chemical behaviour.

Ratio of 35Cl and 37Cl in chlorine :

Let the number be

35Cl = x

37Cl = y

35x, 37y

Atomic mass of chlorine = 35.5

35x+37yx+y\dfrac{35x + 37y}{x+y} = 35.5

35x + 37y = 35.5x + 35.5y
37y - 35.5y = 35.5x - 35x
1.5y = 0.5x
x : y = 3 : 1

The ratio of 35Cl and 37Cl in chlorine will be 3 : 1.

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