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Chemistry

The action of heat on the blue crystalline solid X, gives a reddish brown gas Y, a gas which re-lights a glowing splint and leaves a black residue. When gas Z, which has a rotten egg smell, is passed through a solution of X, a black ppt. is formed.

(a) Identify X, Y and Z.

(b) Write equation for action of heat on X.

(c) Write equation between solution of X and gas Z.

Nitric Acid

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Answer

(a) X is copper nitrate [Cu(NO3)2],
     Y is nitrogen dioxide [NO2] and
     Z is hydrogen sulphide [H2S].

(b) 2Cu(NO3)2 Δ\xrightarrow{\Delta} 2CuO + 4NO2 + O2

(c) When a H2S gas, which has a rotten egg smell, is passed through a solution of Cu(NO3)2, a black ppt. of CuS is formed.
Cu(NO3)2 + H2S ⟶ CuS + 2HNO3

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