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Chemistry

Dilute sulphuric acid is added to sodium sulphite. The following observations are noticed:

P — A gas with a suffocating smell is evolved which turns lime water milky.

Q — A foul smelling gas is evolved which turns lead acetate solution black.

R — A gas is evolved which decolourises pink KMnO4

Which of the following is true?

  1. Only P
  2. Only Q
  3. Only R
  4. Both P and R

Practical Chemistry

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Answer

Both P and R

Reason — When dilute sulphuric acid is added to sodium sulphite, a colourless gas with a smell of burning sulphur i.e., suffocating odour is evolved.

Na2SO3 + H2SO4 ⟶ Na2SO4 + H2O + SO2

This gas turns lime water milky.

Ca(OH)2 + SO2 ⟶ CaSO3↓ + H2O

This gas also decolourises pink KMnO4.

2KMnO4 + 2H2O + 5SO2 ⟶ K2SO4 + 2MnSO4 + 2H2SO4

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