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Chemistry

Distinguish between the following pairs of substances :

(i) Sodium sulphide and sodium sulphite

(ii) HCl gas and chlorine gas

Practical Chemistry

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Answer

(i) On addition of dil. sulphuric acid to sodium sulphide, hydrogen sulphide (H2S) gas is evolved which can be identified by its rotten egg smell. Hydrogen sulphide gas turns moist lead acetate paper silvery black.

Na2S + H2SO4 ⟶ Na2SO4 + H2S ↑

On addition of dil. sulphuric acid to sodium sulphite, sulphur dioxide (SO2) gas is evolved. Sulphur dioxide gas has a suffocating odour and turns lime water milky and potassium permanganate solution from pink to clear colourless.

Na2SO3 + H2SO4 (dil.) ⟶ Na2SO4 + H2O + SO2

(ii) HCl and chlorine gas

Chlorine (Cl2) turns moist starch iodide paper blue black whereas HCl does not.

Cl2 + 2KI ⟶ 2KCl + I2

Starch + I2 ⟶ Blue black colour

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