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Chemistry

Electrolysis is a redox process. Explain.

Electrolysis

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Answer

During electrolysis, the reaction at the cathode involves reduction of cations as they gain electrons to become neutral atoms while that at anode involves oxidation of anions as they lose electrons to become neutral. As redox reactions are reactions where oxidation and reduction takes place simultaneously. Hence, electrolysis is a redox process.

Example : Dissociation of sodium chloride during electrolysis.

NaCl ⇌ Na+ + Cl-

At cathode : Na+ + e- ⟶ Na (reduction)

At anode : Cl- - e- ⟶ Cl (oxidation)

Cl + Cl ⟶ Cl2

Overall reaction: 2NaCl ⟶ 2Na + Cl2

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