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Chemistry

Give examples of eight metals which show variable valency. State the valency of sulphur in :

(a) SO2
(b) SO3

Valency

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Answer

Eight metals which show variable valency are :

1+2+3+4+
CuCu
HgHg
AgAg
Au  Au
  FeFe
  Pb  Pb
  Sn  Sn
  Mn  Mn

(a) Valency of sulphur in SO2 is 4

By interchanging subscript and writing as superscript:

S11  O2S22  O1\underset{\phantom{1}{1}}{\text{S}} \space {\nearrow}\mathllap{\nwarrow} \space \underset{2}{\text{O}} \Rightarrow \overset{\phantom{2}{2}}{\text{S}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{1}{\text{O}} \\[0.5em]

But valency of O is 2. Multiplying by 2, we get:

S2×2  O2×1S44  O2\overset{{2 \times 2}}{\text{S}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{2 \times 1}{\text{O}} \Rightarrow \overset{\phantom{4}{4}}{\text{S}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{2}{\text{O}} \\[0.5em]

Therefore, valency of Sulphur is 4.

(b) Valency of sulphur in SO3 is 6

S11  O3S33  O1\underset{\phantom{1}{1}}{\text{S}} \space {\nearrow}\mathllap{\nwarrow} \space \underset{3}{\text{O}} \Rightarrow \overset{\phantom{3}{3}}{\text{S}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{1}{\text{O}} \\[0.5em]

But valency of O is 2. Multiplying by 2, we get:

S2×3  O2×1S66  O2\overset{{2 \times 3}}{\text{S}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{2 \times 1}{\text{O}} \Rightarrow \overset{\phantom{6}{6}}{\text{S}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{2}{\text{O}} \\[0.5em]

Therefore, valency of Sulphur is 6.

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