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Chemistry

Give reason for the following:

The blue colour of aqueous copper sulphate fades when it is electrolyzed using platinum electrodes.

Electrolysis

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Answer

The blue colour of CuSO4 solution is due to the Cu2+ ions. During it's electrolysis using Pt electrodes, at the cathode Cu2+ ions are discharged as neutral copper atoms by accepting electrons. These are not replaced by Cu2+ ions from the anode because at the anode, OH- ions are discharged. As Cu2+ ions decrease, the blue colour of CuSO4 solution fades and it becomes almost colourless as soon as Cu2+ ions are finished.

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