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Chemistry

Give the general group characteristics applied to hydrogen with respect to similarity in properties of hydrogen with –

(a) alkali metals of group 1 [IA]
(b) halogens of group 17 [VIIA].

with special reference to valency electrons & ion formation.

Hydrogen

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Answer

Similarity in properties of hydrogen with

(a) Alkali metals of group 1 [IA] :

  1. Electronic Configuration — Valency electron - one valence electron e.g., H = 1; Li = 2, 1; Na = 2, 8, 1; K = 2, 8, 8, 1
  2. Ion Formation — Electropositive character exhibited.
    H – 1e ⟶ H1+
    Li – 1e ⟶ Li1+
    Na – 1e ⟶ Na1+
  3. Valency — Electrovalency of 'one' exhibited. H1+, Li1+, Na1+

(b) Halogens of group 17 [VIIA] :

  1. Electronic Configuration — One electron less than the noble gas e.g., H = 1 [He = 2]; F = 2,7; [Ne = 2,8]; Cl = 2,8,7 [Ar = 2,8,8]
  2. Ion Formation — Electronegative character exhibited.
    H + 1e ⟶ H1-
    F + 1e ⟶ F1-
    Cl + 1e ⟶ Cl1-
  3. Valency — Electrovalency and covalency exhibited
    Hydrogen - forms NaH [electrovalent]; CH4 [covalent]
    Chlorine - forms NaCl [electrovalent]; CCl4 [covalent]

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