Chemistry
How will the addition of barium chloride soln. help to distinguish between dil. HCl and dil. H2SO4.
Practical Chemistry
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Answer
Barium chloride reacts with dil H2SO4 to form a white ppt. of barium sulphate.
BaCl2 + H2SO4 [dil.] ⟶ 2HCl + BaSO4 ↓ [white ppt.]
Whereas, dil. HCl does not form a white ppt. Hence, the two can be distinguished.
BaCl2 + HCl [dil.] ⟶ No white ppt.
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Related Questions
Give a reason why carbon dioxide and sulphur dioxide cannot be distinguished by using lime water.
Salts A, B, C, D and E undergo reactions (i) to (v) respectively. Identify the anion present in each salt.
(i) When AgNO3 solution is added to a soln. of A, a white precipitate, insoluble in dilute nitric acid, is formed.
(ii) Addition of dil. HCl to B produces a gas which turns lead acetate paper black.
(iii) When a freshly prepared solution of FeSO4 is added to a soln. of C and conc. H2SO4 is gently poured from the side of the test-tube, a brown ring is formed.
(iv) When dil. H2SO4 is added to D a gas is produced which turns acidified K2Cr2O7 soln. from orange to green.
(v) Addition of dil. HCl to E produced an effervescence. The gas produced turns limewater milky but does not effect acidified K2Cr2O7 soln.
The salt which in solution gives a pale green ppt. with NaOH soln. and a white ppt. with barium chloride solution is :
- Iron (III) sulphate
- Iron (II) sulphate
- Iron (II) chloride
- Iron (III) chloride
CO2 and SO2 gas can be distinguished using :
- moist blue litmus paper
- lime water
- acidified K2Cr2O7 paper
- none of the above.