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Chemistry

(i) Give 2 tests to distinguish between HCl solution and Ammonia solution.

(ii) Distinguish between MnO2 and CuO

Analytical Chemistry

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Answer

(i) Two tests to distinguish between HCl solution and Ammonia solution:

  1. HCl turns moist blue litmus paper red, whereas, ammonia gas turns moist red litmus blue.
  2. With HCl phenolphthalein solution remains colourless whereas, ammonia gas turns it pink.

(ii) Distinguish between MnO2 and CuO:

(a) When each of the compound is heated with conc. hydrochloric acid, greenish yellow (chlorine) gas is evolved in case of manganese dioxide and filtrate is brownish in colour whereas, no chlorine gas is evolved in case of copper oxide and filtrate is bluish in colour.

MnO2 + 4HCl ⟶ MnCl2 + 2H2O + Cl2

CuO + 2HCl ⟶ CuCl2 + H2O

(b) On adding ammonium hydroxide to the above filtrate, no ppt. is formed in case of MnO2, whereas, in case of copper oxide, pale blue ppt. is formed. The ppt. dissolves in excess of ammonium hydroxide forming azure blue colour.

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