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Chemistry

In the laboratory preparation of carbon dioxide by action of a dilute acid on a metallic carbonate give -

(a) A balanced equation for the preparation

(b) A reason for

(i) use of a washer bottle containing conc. H2SO4 in the preparation

(ii) Not collecting the prepared gas over water

(iii) Not using dilute sulphuric acid as a reactant in the preparation.

Carbon dioxide

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Answer

(a) CaCO3 + 2HCl [dil.] ⟶ CaCl2 + H2O + CO2

(b) (i) The evolved carbon dioxide is passed through the washer bottles containing conc. H2SO4, to absorb moisture.

(ii) Carbon dioxide is fairly soluble in water, hence, it is not collected over water,

(iii) Dilute sulphuric acid reacts with calcium carbonate forming a coating of insoluble calcium sulphate on the marble chips thereby the reaction slowly comes to a stop.
CaCO3 + H2SO4 [dil.] ⟶ CaSO4 [insoluble] + H2O + CO2

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