Chemistry
State the defects of the table proposed by Mendeleev.
Periodic Table
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Answer
Defects of table proposed by Mendeleev:
- Anomalous pairs — The following elements did not follow Mendeleev's principles:
- Argon with atomic mass 39.9 precedes potassium with atomic mass 39.1
- Cobalt with atomic mass 58.9 precedes nickel with atomic mass 58.6
- Tellurium with atomic mass 127.6 precedes iodine with atomic mass 126.9
- Position of isotopes — According to Mendeleev's periodic table isotopes should be given separate place in the table since they have different atomic mass. But they were not assigned separate places.
- Grouping of chemically dissimilar elements — Elements such as copper and silver bear no resemblance to alkali metals (lithium, sodium etc.) but they have been placed together in the first group.
- Separation of chemically similar elements — Elements that are chemically similar, such as gold and platinum have been placed in separate groups.
- Electron arrangement — It does not explain the electron arrangement of elements.
- Position of hydrogen — Hydrogen was not given a fixed position. It was considered in group IA as well as in group VIIA because it forms both a positive ion, viz. in HCl and a negative ion, viz. in NaH.
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