Chemistry
State what are oxidising and reducing agents. Give examples of oxidising and reducing agents in the gaseous, liquid and solid form. Give two tests each generally answered by oxidising and reducing agents respectively.
Hydrogen
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Answer
Oxidizing Agents :
- Loses oxygen or electronegative radical
- Gains hydrogen or electropositve radical
- Accepts electrons.
Examples:
- Gases - O2, O3, Cl2, F2
- Liquids - H2O2, K2Cr2O7 [acidified], conc. HNO3, conc. H2SO4
- Solids - MnO2, HgCl2, PbO2, KNO3
Reducing Agents :
- Gains oxygen or electronegative radical
- Loses hydrogen or electropositive radical
- Donates electrons.
Examples:
- Gases - H2, CO, SO2, NH3
- Liquids - HCl, HBr, H2SO3, HNO2
- Solids - Carbon [coke], metals [K, Na, Ca], Sugar [C12H22O11], SnCl2
Test for an Oxidizing Agent :
- Decomposes to give a colourless gas which rekindles a glowing splint.
- Liberates chlorine on heating with conc. HCl
Test for a Reducing Agent :
- On reaction with iron[III] salts - the colour changes from yellowish brown to light green [iron [II] ions are formed].
- Liberates nitrogen dioxide on heating with conc. HNO3.
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Explain the terms – oxidation and reduction in terms of addition and removal of oxygen/hydrogen with suitable examples.
Explain the term redox reaction with an example involving the reaction of hydrogen sulphide with chlorine.
Select from A to G the reactant added, to give the products 1 to 5, in the preparation of hydrogen gas.
A : dilute acid
B : dilute alkali
C : cold water
D : conc. alkali
E : boiling water
F : conc. acid
G : steam- Ca(OH)2 + H2
- MgO + H2
- Fe3O4 + H2
- Al2(SO4)3 + H2
- NaAlO2 + H2
Give balanced equations for the following conversions, 1 to 5.
- MgCl2 ⟵ HCl ⟶ FeCl2
- KAlO2 ⟵ KOH ⟶ K2ZnO2
- ZnO ⟵ H2O ⟶ Fe3O4
- CO + H2 ⟵ H2O ⟶ CO2 + H2
- NH3 ⟵ H2 ⟶ H2S