Chemistry
To carry out the so-called 'electrolysis of water', sulphuric acid is added to water. How does the addition of sulphuric acid produce a conducting solution?
Electrolysis
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Answer
Water in pure state consists almost entirely of molecules. Hence it is a non-electrolyte that will not conduct electricity.
Water is a polar covalent compound. It can be electrolytically decomposed by addition of traces of dil. H2SO4 which dissociates as: H+1 and SO42- and help in dissociating water into H+1 and OH- ions. Thus, dilute sulphuric acid catalyses the ionisation of water to produce a conducting solution.
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Related Questions
During electrolysis of an aqueous solution of sulphuric acid between platinum electrodes, two types of anions migrate towards the anode but only one of them is discharged.
(a) Name the two anions.
(b) Name the main product of the discharge of anion at the anode and write the anode reaction.
(c) Name the product at the cathode and write the reaction.
(d) Do you notice any change in colour? State why?
(e) Why this electrolysis is considered as an example of catalysis?
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(a) Give the names of the electrodes A and B.
(b) Which electrode is the oxidising electrode?
(a) Choosing only words from the following list, write down the appropriate words to fill in the blanks (i) to (v) below:
anions , anode, cathode, cations , electrode, electrolyte, nickel , voltameter.
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Explain the following :
A solution of cane sugar does not conduct electricity, but a solution of sodium chloride is a good conductor.