Chemistry
(a) Explain the terms 'valency' and 'variable valency'.
(b) How are the elements with variable valency named ? Explain with an example.
Valency
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Answer
(a) Valency is the combining capacity of an atom or of a radical. The valency of an element or of a radical is the number of hydrogen atoms that will combine with or displace one atom of that element or radical.
Variable valency is the ability of certain elements to have more than one valency or different combining capacities. An atom of an element can sometimes lose more electrons than are present in its valence shell, i.e., there is a loss of electrons from the penultimate shell too. Such element is said to exhibit variable valency.
(b) If an element exhibits two different positive valencies, then the suffix "ous" is used for the lower valency and the suffix "ic" is used for the higher valency. Modern chemists use Roman numerals in place of these trivial names.
For example, Iron can exhibit a valency of +2 or +3. The ion with valency +2 is named as Ferrous ion (Fe2+) and with valency +3 is named as Ferric ion (Fe3+). Its oxides will be named as Ferrous oxide or Iron (II) oxide [FeO] and Ferric oxide or Iron (III) oxide [Fe2O3].
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