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Chemistry

Ammonia is formed from the reactants nitrogen and hydrogen in presence of a catalyst under suitable conditions. Assuming all volumes are measured in litres at s.t.p. Calculate the volume of ammonia formed if only 10% conversion has taken place.

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Answer

[By Lussac's law]

N2+3H22NH31 vol.:3 vol.2 vol.1 lit.:3 lit.2 lit.\begin{matrix} \text{N}2 & + & 3\text{H}2 & \longrightarrow & 2\text{NH}_3 & \ 1 \text{ vol.} & : & 3 \text{ vol.} & \longrightarrow & 2 \text{ vol.} & \ 1 \text{ lit.} & : & 3 \text{ lit.} & \longrightarrow & 2 \text{ lit.} & \end{matrix}

To calculate the volume of ammonia formed when only 10% conversion takes place,

10% of 2 lit=10100×2=0.2 lit\therefore 10\% \text{ of 2 lit} = \dfrac{10}{100} \times 2 = 0.2 \text{ lit}

Hence, volume of ammonia formed is 0.2 lit or 20% or 1/5th of vol of N2 and H2

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