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Chemistry

What is the valency of nitrogen in :

(i) NO

(ii) N2O

(iii) NO2

Valency

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Answer

(i) NO=N11  O1N11  O1\text{(i)} \space \text{NO} = \underset{\phantom{1}{1}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \underset{1}{\text{O}} \Rightarrow \overset{\phantom{1}{1}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{1}{\text{O}} \\[0.5em]

But valency of O is 2. Multiplying by 2, we get:

N2×1  O2×1N22  O2\overset{{2 \times 1}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{2 \times 1}{\text{O}} \Rightarrow \overset{\phantom{2}{2}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{2}{\text{O}} \\[0.5em]

Therefore, valency of Nitrogen is 2.

(ii) N2O=N22  O1N11  O2\text{(ii)} \space \text{N}_2\text{O} = \underset{\phantom{2}{2}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \underset{1}{\text{O}} \Rightarrow \overset{\phantom{1}{1}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{2}{\text{O}} \\[0.5em]

Therefore, valency of Nitrogen is 1.

(ii) NO2=N11  O2N22  O1\text{(ii)} \space \text{NO}_2 = \underset{\phantom{1}{1}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \underset{2}{\text{O}} \Rightarrow \overset{\phantom{2}{2}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{1}{\text{O}} \\[0.5em]

But valency of O is 2. Multiplying by 2, we get:

N2×2  O2×1N44  O2\overset{{2 \times 2}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{2 \times 1}{\text{O}} \Rightarrow \overset{\phantom{4}{4}}{\text{N}} \space {\nearrow}\mathllap{\nwarrow} \space \overset{2}{\text{O}} \\[0.5em]

Therefore, valency of Nitrogen is 4.

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